SO I always put up a hand-painted color wheel, and a blank one. We mix the colors together one by one and they fill out a "color strip" on the top of their paintings (not pictured). This helps them differentiate between the 3 groups of colors and to remember to use ONLY tertiary in their paintings.
Tertiary colors can be tough because each is a color that is neither one color, nor another. For example, yellow-green is not recognizable as yellow nor green, and the same for red-orange, etc. So for them to be able to decide when to stop mixing/adding color as they have achieved the tertiary hue is a big high five for my students.
The first week of class, we did the color swatch strip, and then painted black contour lines of vases and flowers from a poster which I provided with simple flower shapes. Important not to make the flowers too detailed, as they are reminded it will be hard to paint inside the black lines with the brushes I am provided.
All in all I think my students learned quite a lot out of this lesson!